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In Fall of 2024, central Florida was impacted by Hurricane Helene (landfall in Perry, FL as a Cat 4 hurricane on Sept 27) and by Hurricane Milton (landfall in Siesta Key, FL as Cat 3 on Oct 9). The hurricanes led to damages of an estimated value > $200billion. The Nearshore Extreme Events Reconnaissance Association (NEER) and the Geotechnical Extreme Events Reconnaissance Association (GEER) represented by their members from more than 10 academic institutions, federal agencies, and industry and supported by technical staff from the NHERI RAPID facility and the UF Center for Coastal Solutions initiated on Sept 23 a data collection effort that included pre-, during-, and post-storm multi-disciplinary data collections efforts. The field data collection effort was concluded on Nov 22. Data includes hydraulic information on storm surge, waves, and currents, topographic and bathymetric data sets, terrestrial and seabed mapping, and geotechnical site characterization including in-situ testing, sediment sampling, and seismic testing. Data was collected in four focus areas in Florida (Cedar Key; Horseshoe Beach; Midnight Pass and Milton Pass, both near Venice) and observational data and limited data products were collected in other areas in Florida including Orchid, Ponte Vedra, Suwannee, Panama City, and others. Data is organized by site (four primary sites and others); data collection phase with respect to the two hurricanes; and instruments or data collection method. This work included support from both the UF Center for Coastal Solutions and the NHERI RAPID facility. 

Cerium oxide nanoparticles (CeNPs) are versatile materials with unique and unusual properties that vary depending on their surface chemistry, size, shape, coating, oxidation states, crystallinity, dopant, structural and surface defects. This review details advances made over the past twenty years in the development of CeNPs and ceria-based nanostructures, the structural determinants affecting their activity, and translation of these distinct features into applications. The two-oxidation states of nanosized CeNPs (Ce3+/Ce4+) coexisting at the nanoscale level, facilitate formation of oxygen vacancies and defect states which confer extremely high reactivity and oxygen buffering capacity, and the ability to act as catalysts for oxidation and reduction reactions. However, the method of synthesis, surface functionalization, surface coating and defects are important factors in determining their properties. This review highlights the key properties of CeNPs, their synthesis, interactions and reaction pathways, and provides examples of emerging applications. Due to their unique properties, CeNPs have become quintessential candidates for catalysis, chemical mechanical planarization (CMP), sensing, biomedical applications and environmental remediation, with tremendous potential to create novel products and translational innovations in a wide range of industries. This review highlights the timely relevance and the transformative potential of these materials in addressing societal challenges and driving technological advancements across these fields. 

An environmentally responsible synthesis of Na_2/3[Ni_1/3Mn_2/3]O₂(NNMO) enabled by direct conversion of metallic Ni powder, releasing only O₂and H₂O as byproducts. The resulting NNMO exhibits excellent cycling performance as a Na-ion battery cathode. 

Traditionally, FPGA programming has been done via a hardware description language (HDL). An HDL provides fine-grained control over reconfigurable hardware but with limited productivity due to a steep learning curve and tedious design cycle. Thus, high-level synthesis (HLS) approaches have been a significant boon to productivity, and in recent years, OpenCL has emerged as a vendor-agnostic HLS language that offers the added benefit of interoperation with other OpenCL platforms (e.g., CPU, GPU, DSP) and existing OpenCL software. However, OpenCL's productivity can also suffer from tedious boilerplate code and the need to manually coordinate the host (i.e., CPU) and device (i.e., FPGA or other device). So, we present MetaCL, a compiler-assisted interface that takes OpenCL kernel functions as input and automatically generates OpenCL host-side code as output. MetaCL produces more efficient and readable host-side code, ensures portability, and introduces minimal additional runtime overhead compared to unassisted OpenCL development. 

Abstract Nanoelectrochemistry allows for the investigation of the interaction of per‐ and polyfluoroalkyl substances (PFASs) with silver nanoparticles (AgNPs) and the elucidation of the binding behaviour of PFASs to nanoscale surfaces with high sensitivity. Mechanistic studies supported by single particle collision electrochemistry (SPCE), spectroscopic and density functional theory (DFT) calculations indicate the capability of polyfluorooctane sulfonic acid (PFOS), a representative PFAS, to selectively bind and induce aggregation of AgNPs. Single‐particle measurements provide identification of the “discrete” AgNPs agglomeration (e.g. 2–3 NPs) formed through the inter‐particles F−F interactions and the selective replacement of the citrate stabilizer by the sulfonate of the PFOS. Such interactions are characteristic only for long chain PFAS (‐SO₃⁻) providing a means to selectively identify these substances down to ppt levels. Measuring and understanding the interactions of PFAS at nanoscale surfaces are crucial for designing ultrasensitive methods for detection and for modelling and predicting their interaction in the environment.